Raman's elder brother Chandrasekhara Subrahmanya Ayyar had joined the prestigious Indian government service, Indian Finance Service (now Indian Audit and Accounts Service). Raman followed suit and qualified for the Indian Finance Service achieving first position in the entrance examination in February 1907. He was posted in Calcutta (now Kolkata) as Assistant Accountant General in June 1907.
From 1915, the University of Calcutta started assigning research scholars under Raman at IACS. Sudhangsu Kumar Banerji (who later become Director General of Observatories of India Meteorological Department), a PhD scholar under Ganesh Prasad, was his first student. From the next year, other universities followed suit including University of Allahabad, Rangoon University, Queen's College Indore, Institute of Science, Nagpur, Krisnath College, and University of Madras. By 1919, Raman had guided more than a dozen students. Following Sircar's death in 1919, Raman received two honorary positions at IACS, Honorary Professor and Honorary Secretary. He referred to this period as the "golden era" of his life.
Raman's appointment as the Palit Professor was strongly objected to by some members of the Senate of the University of Calcutta, especially foreign members, as he had no PhD and had never studied abroad. As a kind of rebuttal, Asutosh Mukherjee arranged for an honorary DSc which the University of Calcutta conferred Raman in 1921. The same year he visited Oxford to deliver a lecture at the Congress of Universities of the British Empire. He had earned quite a reputation by then, and his hosts were Nobel laureates J. J. Thomson and Lord Rutherford. Upon his election as Fellow of the Royal Society in 1924, Mukherjee asked him of his future plans, which he replied, saying, "The Nobel Prize of course." In 1926, he established the Indian Journal of Physics and acted as the first editor. The second volume of the journal published his famous article "A new radiation", reporting the discovery of the Raman effect.
One of Raman's interests was on the scientific basis of musical sounds. He was inspired by Hermann von Helmholtz's The Sensations of Tone, the book he came across when he joined IACS. He published his findings prolifically between 1916 and 1921. He worked out the theory of transverse vibration of bowed string instruments based on superposition of velocities. One of his earliest studies was on the wolf tone in violins and cellos. He studied the acoustics of various violin and related instruments, including Indian stringed instruments, and water splashes. He even performed what he called "Experiments with mechanically-played violins."
Raman, in his broadening venture on optics, started to investigate scattering of light starting in 1919. His first phenomenal discovery of the physics of light was the blue color of seawater. During a voyage home from England on board the S.S. Narkunda in September 1921, he contemplated the blue color of the Mediterranean Sea. Using simple optical equipment, a pocket-sized spectroscope and a Nicol prism in hand, he studied the sea water. Of several hypotheses on the colour of the sea propounded at the time, the best explanation had been that of Lord Rayleigh's in 1910, according to which, "The much admired dark blue of the deep sea has nothing to do with the color of water, but is simply the blue of the sky seen by reflection". Rayleigh had correctly described the nature of the blue sky by a phenomenon now known as Rayleigh scattering, the scattering of light and refraction by particles in the atmosphere. His explanation of the blue colour of water was instinctively accepted as correct. Raman could view the water using a Nicol prism to avoid the influence of sunlight reflected by the surface. He described how the sea appears even more blue than usual, contradicting Rayleigh.
When he reached Calcutta, he asked his student K. R. Ramanathan, who was from the University of Rangoon, to conduct further research at IACS. By early 1922, Raman came to a conclusion, as he reported in the Proceedings of the Royal Society of London:
True to his words, Ramanathan published an elaborate experimental finding in 1923. His subsequent study of the Bay of Bengal in 1924 provided the full evidence. It is now known that the intrinsic color of water is mainly attributed to the selective absorption of longer wavelengths of light in the red and orange regions of the spectrum, owing to overtones of the infrared absorbing O-H (oxygen and hydrogen combined) stretching modes of water molecules.
Raman's second important discovery on the scattering of light was a new type of radiation, an eponymous phenomenon called the Raman effect. After discovering the nature of light scattering that caused blue colour of water, he focused on the principle behind the phenomenon. His experiments in 1923 showed the possibility of other light rays formed in addition to the incident ray when sunlight was filtered through a violet glass in certain liquids and solids. Ramanathan believed that this was a case of a "trace of fluorescence." In 1925, K. S. Krishnan, a new Research Associate, noted the theoretical background for the existence of an additional scattering line beside the usual polarised elastic scattering when light scatters through liquid. He referred to the phenomenon as "feeble fluorescence." But the theoretical attempts to justify the phenomenon were quite futile for the next two years.
But the origin of the inspiration went further. As Compton later recollected "that it was probably the Toronto debate that led him to discover the Raman effect two years later." The Toronto debate was about the discussion on the existence of light quantum at the British Association for the Advancement of Science meeting held at Toronto in 1924. There Compton presented his experimental findings, which William Duane of Harvard University argued with his own with evidence that light was a wave. Raman took Duane's side and said, "Compton, you're a very good debater, but the truth isn't in you."
Krishnan started the experiment in the beginning of January 1928. On 7 January, he discovered that no matter what kind of pure liquid he used, it always produced polarised fluorescence within the visible spectrum of light. As Raman saw the result, he was astonished why he never observed such phenomenon all those years. That night he and Krishnan named the new phenomenon as "modified scattering" with reference to the Compton effect as an unmodified scattering. On 16 February, they sent a manuscript to Nature titled "A new type of secondary radiation", which was published on 31 March.
On 28 February 1928, they obtained spectra of the modified scattering separate from the incident light. Due to difficulty in measuring the wavelengths of light, they had been relying on visual observation of the colour produced from sunlight through prism. Raman had invented a type of spectrograph for detecting and measuring electromagnetic waves. Referring to the invention, Raman later remarked, "When I got my Nobel Prize, I had spent hardly 200 rupees on my equipment," although it was obvious that his total expenditure for the entire experiment was much more than that. From that moment they could employ the instrument using monochromatic light from a mercury arc lamp which penetrated transparent material and was allowed to fall on a spectrograph to record its spectrum. The lines of scattering could now be measured and photographed.
Some physicists, particularly French and German physicists were initially sceptical of the authenticity of the discovery. Georg Joos at the Friedrich Schiller University of Jena asked Arnold Sommerfeld at the University of Munich, "Do you think that Raman's work on the optical Compton effect in liquids is reliable?... The sharpness of the scattered lines in liquids seems doubtful to me". Sommerfeld then tried to reproduce the experiment, but failed. On 20 June 1928, Peter Pringsheim at the University of Berlin was able to reproduce Raman's results successfully. He was the first to coin the terms Ramaneffekt and Linien des Ramaneffekts in his articles published the following months. Use of the English versions, "Raman effect" and "Raman lines" immediately followed.
In addition to being a new phenomenon itself, the Raman effect was one of the earliest proofs of the quantum nature of light. Robert W. Wood at the Johns Hopkins University was the first American to confirm the Raman effect in early 1929. He made a series of experimental verification, after which he commented, saying, "It appears to me that this very beautiful discovery which resulted from Raman's long and patient study of the phenomenon of light scattering is one of the most convincing proofs of the quantum theory". The field of Raman spectroscopy came to be based on this phenomenon, and Ernest Rutherford, President of the Royal Society, referred to it in his presentation of the Hughes Medal to Raman in 1930 as "among the best three or four discoveries in experimental physics in the last decade".
Raman was confident that he would win the Nobel Prize in Physics as well but was disappointed when the Nobel Prize went to Owen Richardson in 1928 and to Louis de Broglie in 1929. He was so confident of winning the prize in 1930 that he booked tickets in July, even though the awards were to be announced in November. He would scan each day's newspaper for announcement of the prize, tossing it away if it did not carry the news. He did eventually win that year.
Other investigations he carried out included experimental and theoretical studies on the diffraction of light by acoustic waves of ultrasonic and hypersonic frequencies, and those on the effects produced by X-rays on infrared vibrations in crystals exposed to ordinary light which were published between 1935 and 1942.
Raman married Lokasundari Ammal, daughter of S. Krishnaswami Iyer who was the Superintendent of Sea Customs at Madras, in 1907. The wedding day is popularly recorded as on 6 May, but Raman's great-niece and biographer, Uma Parameswaran, revealed a factual date of 2 June 1907. It was a self-arranged marriage and his wife was 13 years old. (Sources are contradicting on her age as her birth year is specified as 1892, which would make her about 15 years of age; but Parameswaran affirmed the 13-year, corroborated by her obituary in Current Science that mentioned her age as 86 on her death on 22 May 1980.) His wife later jokingly recounted that their marriage was not so much about her musical prowess (she was playing veena when they first met) as "the extra allowance which the Finance Department gave to its married officers." The extra allowance refers to an additional INR 150 for married officers at the time. Soon after they moved to Calcutta in 1907, the couple were accused of converting to Christianity. It was because they frequently visited St. John's Church, Kolkata as Lokasundari was fascinated with the church music and Raman with the acoustics.
Throughout his life, Raman developed an extensive personal collection of stones, minerals, and materials with interesting light-scattering properties, which he obtained from his world travels and as gifts. He often carried a small, handheld spectroscope to study specimens. These, along with his spectrograph, are on display at IISc.
Lord Rutherford was instrumental in some of Raman's most pivotal moments in life. He nominated Raman for the Nobel Prize in Physics in 1930, presented him the Hughes Medal as President of the Royal Society in 1930, and recommended him for the position of Director at IISc in 1932.
Raman had a sense of obsession with the Nobel Prize. In a speech at the University of Calcutta, he said, "I'm not flattered by the honour [Fellowship to the Royal Society in 1924] done to me. This is a small achievement. If there is anything that I aspire for, it is the Nobel Prize. You will find that I get that in five years." He knew that if he were to receive the Nobel Prize, he could not wait for the announcement of the Nobel Committee normally made towards the end of the year considering the time required to reach Sweden by sea route. With confidence, he booked two tickets, one for his wife, for a steamship to Stockholm in July 1930. Soon after he received the Nobel Prize, he was asked in an interview the possible consequences if he had discovered the Raman effect earlier, which he replied, "Then I should have shared the Nobel Prize with Compton and I should not have liked that; I would rather receive the whole of it."
On his deathbed, he said to his wife, "I believe only in the Spirit of Man," and asked for his funeral, "Just a clean and simple cremation for me, no mumbo-jumbo please."
Two days before Raman died, he told one of his former students, "Do not allow the journals of the Academy to die, for they are the sensitive indicators of the quality of science being done in the country and whether science is taking root in it or not." That evening, Raman met with the Board of Management of his institute in his bedroom and discussed with them the fate of the institute's management. He also willed his wife to perform a simple cremation without any rituals upon his death. He died from natural causes early the next morning on 21 November 1970 at the age of 82.
Krishnan was not nominated for the Nobel Prize even though he was the main researcher in discovering the Raman effect. He alone first noted the new scattering. Krishnan co-authored all the scientific papers on the discovery in 1928 except two. He alone wrote all the follow-up studies. Krishnan himself never claimed himself worthy of the prize. But Raman admitted later that Krishnan was the co-discoverer. He however remained openly antagonistic towards Krishnan, which the latter described as "the greatest tragedy of my life." After Krishnan's death, Raman said to a correspondent from The Times of India, "Krishnan was the greatest charlatan I have known, and all his life he masqueraded in the cloak of another man's discovery.": 251
In this dispute, Born received support from most physicists, as his view was proven to be a better explanation. Raman's theory was generally regarded as having partial relevance. Beyond the intellectual debate, their rivalry extended to personal and social levels. Born later said that Raman probably thought of him as an "enemy." Despite the mounting evidence for Born's theory, Raman refused to concede. As the editor of Current Science he rejected articles that supported Born's theory. Born was nominated several times for the Nobel Prize specifically for his contributions to lattice theory, and eventually won it for his statistical works on quantum mechanics in 1954. The account was written as a "belated Nobel Prize."
On the same occasion Nehru, offered Raman financial assistance to his institute which Raman flatly refused by replying, "I certainly don't want this to become another government laboratory." Raman was particularly against the control of research programmes by the government such as in the establishment of the Bhabha Atomic Research Centre (BARC), Defence Research and Development Organisation (DRDO), and the Council of Scientific and Industrial Research (CSIR). He remained hostile to people associated with these establishments including Homi J. Bhabha, S.S. Bhatnagar, and his once favourite student, Krishnan. He even called such programmes as the "Nehru–Bhatnagar effect." In 1959, Raman proposed to establish another research institute in Madras. The Government of Madras advised him to apply for funds from the central government. But Raman clearly foresaw as he replied to C. Subramaniam, then the Minister for Finance Education in Madras, that his proposal to Nehru's government "would be met with a refusal." So ended the plan.
The Indian Academy of Sciences was born out of conflicts during the procedures of the proposal for a national scientific organization in line with the Royal Society. In 1933, the Indian Science Congress Association (ISCA), at the time the largest scientific organization, planned to establish a national science body, which would be authorized to advise the government on scientific matters. Sir Richard Gregory, then editor of Nature, on his visit to India had suggested Raman, as editor of Current Science, to establish an Indian Academy of Sciences. Raman thought that it should be an exclusively Indian membership as opposed to the general consensus that British members should be included. He resolved "How can India Science prosper under the tutelage of an academy which has its own council of 30, 15 of who are Britishers of whom only two or three are fit enough to be its Fellows." On 1 April 1933, he convened a separate meeting of the South Indian scientists. He and Subba Rao officially resigned from ISCA.
Raman registered the new organization as the Indian Academy of Sciences on 24 April to the Registrar of Societies. It was a provisional name to be changed to the Royal Society of India after approval from the Royal Charter. The Government of India did not recognize it as an official national scientific body, as such the ICSA created a separate organization named the National Institute of Sciences of India on 7 January 1935 (but again changed to the Indian National Science Academy in 1970). INSA had been led by the foremost rivals of Raman including Meghnad Saha, Bhabha, Bhatnagar, and Krishnan.
Raman had a great fallout with the authorities at the Indian Institute of Science (IISc). He was accused of biased development in physics while ignoring other fields. He lacked diplomatic personality with other colleagues, which S. Ramaseshan, his nephew and later Director of IISc, reminisced, saying, "Raman went in there like a bull in a china shop." He wanted research in physics at the level of those of western institutes, but at the expense of other fields of science. Max Born observed, "Raman found a sleepy place where very little work was being done by a number of extremely well–paid people." At the Council meeting, Kenneth Aston, professor in the Electrical Technology Department, harshly criticized Raman and Raman's recruitment of Born. Raman had every intention of giving the full position of professor to Born. Aston even made a personal attack on Born by referring to him as someone "who was rejected by his own country, a renegade and therefore a second-rate scientist unfit to be part of the faculty, much less to be the head of the department of physics."
The Council of IISc constituted a review committee to oversee Raman's conduct in January 1936. The committee, chaired by James Irvine, Principal and Vice-Chancellor of the University of St Andrews, reported in March that Raman had misused the funds and entirely shifted the "centre of gravity" towards research in physics, and also that the proposal of Born as Professor of Mathematical Physics (which was already approved by the Council in November 1935) was not financially feasible. The Council offered Raman two choices, either to resign from the institute with effect from 1 April or resign as the Director and continue as Professor of physics; if he did not make the choice, he was to be fired. Raman was inclined to take up the second choice.
Raman never seemed to have thought highly of the Fellowship of the Royal Society. He tendered his resignation as a Fellow on 9 March 1968, which the Council of the Royal Society accepted on 4 April. However, the exact reason was not documented. One reason could be Raman's objection to the designation "British subjects" as one of the categories of the Fellows. Particularly after the Independence of India, the Royal Society had its own disputes on this matter.
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