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Isotopes of moscovium
Isotopes of chemical element moscovium

Moscovium (115Mc) is a synthetic element, and thus a standard atomic weight cannot be given. Like all synthetic elements, it has no known stable isotopes. The first isotope to be synthesized was 288Mc in 2004. There are five known radioisotopes from 286Mc to 290Mc. The longest-lived isotope is 290Mc with a half-life of 0.65 seconds.

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List of isotopes

The isotopes undergo alpha decay into the corresponding isotope of nihonium, with half-lives increasing as neutron numbers increase.

NuclideZNIsotopic mass (Da)123Half-life4Decaymode5DaughterisotopeSpin andparity6
286Mc711517120+98−9 msα282Nh
287Mc115172287.19082(48)#38+22−10 ms8α283Nh
288Mc115173288.19288(58)#193+15−13 ms9α284Nh
289Mc115174289.19397(83)#250+51−35 ms10α285Nh
290Mc11115175290.19624(64)#650+490−200 ms[0.84(36) s]α286Nh
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Nucleosynthesis

Chronology of isotope discovery
IsotopeYear discoveredDiscovery reaction
286Mc2021243Am(48Ca,5n)
287Mc2003243Am(48Ca,4n)
288Mc2003243Am(48Ca,3n)
289Mc2009249Bk(48Ca,4n)12
290Mc2009249Bk(48Ca,3n)13

Target-projectile combinations

The table below contains various combinations of targets and projectiles which could be used to form compound nuclei with Z = 115. Each entry is a combination for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.

TargetProjectileCNAttempt result
208Pb75As283McReaction yet to be attempted
209Bi76Ge285McReaction yet to be attempted
238U51V289McFailure to date
243Am48Ca291Mc1415Successful reaction
241Am48Ca289McPlanned reaction
243Am44Ca287McReaction yet to be attempted

Hot fusion

Hot fusion reactions are processes that create compound nuclei at high excitation energy (~40–50 MeV, hence "hot"), leading to a reduced probability of survival from fission. The excited nucleus then decays to the ground state via the emission of 3–5 neutrons. Fusion reactions utilizing 48Ca nuclei usually produce compound nuclei with intermediate excitation energies (~30–35 MeV) and are sometimes referred to as "warm" fusion reactions. This leads, in part, to relatively high yields from these reactions.

238U(51V,xn)289−xMc

There are strong indications that this reaction was performed in late 2004 as part of a uranium(IV) fluoride target test at the GSI. No reports have been published suggesting that no product atoms were detected, as anticipated by the team.16

243Am(48Ca,xn)291−xMc (x=2,3,4,5)

This reaction was first performed by the team in Dubna in July–August 2003. In two separate runs they were able to detect 3 atoms of 288Mc and a single atom of 287Mc. The reaction was studied further in June 2004 in an attempt to isolate the descendant 268Db from the 288Mc decay chain. After chemical separation of a +4/+5 fraction, 15 SF decays were measured with a lifetime consistent with 268Db. In order to prove that the decays were from dubnium-268, the team repeated the reaction in August 2005 and separated the +4 and +5 fractions and further separated the +5 fractions into tantalum-like and niobium-like ones. Five SF activities were observed, all occurring in the niobium-like fractions and none in the tantalum-like fractions, proving that the product was indeed isotopes of dubnium.

In a series of experiments between October 2010 – February 2011, scientists at the FLNR studied this reaction at a range of excitation energies. They were able to detect 21 atoms of 288Mc and one atom of 289Mc, from the 2n exit channel. This latter result was used to support the synthesis of tennessine. The 3n excitation function was completed with a maximum at ~8 pb. The data was consistent with that found in the first experiments in 2003.

This reaction was run again at five different energies in 2021 to test the new gas-filled separator at Dubna's SHE-factory. They detected 6 chains of 289Mc, 58 chains of 288Mc, and 2 chains of 287Mc. For the first time the 5n channel was observed with 2 atoms of 286Mc.17

242Pu(50Ti,pxn)291−xMc (x=2)

This reaction was studied by the team in Dubna in 2024. For the first time, a pxn reaction was successful with actinide targets and 48Ca/50Ti/54Cr projectiles, producing one atom of the known 289Mc in the p2n channel (evaporating one proton and two neutrons).18

Reaction yields

The table below provides cross-sections and excitation energies for hot fusion reactions producing moscovium isotopes directly. Data in bold represent maxima derived from excitation function measurements. + represents an observed exit channel.

ProjectileTargetCN2n3n4n5n
48Ca243Am291Mc3.7 pb, 39.0 MeV0.9 pb, 44.4 MeV

Theoretical calculations

Decay characteristics

Theoretical calculations using a quantum-tunneling model support the experimental alpha-decay half-lives.19

Evaporation residue cross sections

The table below contains various target-projectile combinations for which calculations have provided estimates for cross section yields from various neutron evaporation channels. The channel with the highest expected yield is given.

MD = multi-dimensional; DNS = Di-nuclear system; σ = cross section

TargetProjectileCNChannel (product)σmaxModelRef
243Am48Ca291Mc3n (288Mc)3 pbMD20
243Am48Ca291Mc4n (287Mc)2 pbMD21
243Am48Ca291Mc3n (288Mc)1 pbDNS22
242Am48Ca290Mc3n (287Mc)2.5 pbDNS23
241Am48Ca289Mc4n (285Mc)1.04 pbDNS24

References

  1. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf. /wiki/Doi_(identifier)

  2. ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.

  3. # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).

  4. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae. https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf

  5. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae. https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf

  6. Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae. https://www-nds.iaea.org/amdc/ame2020/NUBASE2020.pdf

  7. Oganessian, Yu. Ts.; Utyonkov, V. K.; Kovrizhnykh, N. D.; et al. (2022). "New isotope 286Mc produced in the 243Am+48Ca reaction". Physical Review C. 106 (64306): 064306. Bibcode:2022PhRvC.106f4306O. doi:10.1103/PhysRevC.106.064306. S2CID 254435744. https://doi.org/10.1103%2FPhysRevC.106.064306

  8. Oganessian, Yu. Ts.; Utyonkov, V. K.; Kovrizhnykh, N. D.; et al. (2022). "New isotope 286Mc produced in the 243Am+48Ca reaction". Physical Review C. 106 (64306): 064306. Bibcode:2022PhRvC.106f4306O. doi:10.1103/PhysRevC.106.064306. S2CID 254435744. https://doi.org/10.1103%2FPhysRevC.106.064306

  9. Oganessian, Yu. Ts.; Utyonkov, V. K.; Kovrizhnykh, N. D.; et al. (2022). "New isotope 286Mc produced in the 243Am+48Ca reaction". Physical Review C. 106 (64306): 064306. Bibcode:2022PhRvC.106f4306O. doi:10.1103/PhysRevC.106.064306. S2CID 254435744. https://doi.org/10.1103%2FPhysRevC.106.064306

  10. Oganessian, Yu. Ts.; Utyonkov, V. K.; Kovrizhnykh, N. D.; et al. (2022). "New isotope 286Mc produced in the 243Am+48Ca reaction". Physical Review C. 106 (64306): 064306. Bibcode:2022PhRvC.106f4306O. doi:10.1103/PhysRevC.106.064306. S2CID 254435744. https://doi.org/10.1103%2FPhysRevC.106.064306

  11. Not directly synthesized, created as decay product of 294Ts

  12. Oganessian, Yuri Ts.; Abdullin, F. Sh.; Bailey, P. D.; et al. (2010-04-09). "Synthesis of a New Element with Atomic Number Z=117". Physical Review Letters. 104 (142502). American Physical Society: 142502. Bibcode:2010PhRvL.104n2502O. doi:10.1103/PhysRevLett.104.142502. PMID 20481935. https://www.researchgate.net/publication/44610795

  13. Oganessian, Yuri Ts.; Abdullin, F. Sh.; Bailey, P. D.; et al. (2010-04-09). "Synthesis of a New Element with Atomic Number Z=117". Physical Review Letters. 104 (142502). American Physical Society: 142502. Bibcode:2010PhRvL.104n2502O. doi:10.1103/PhysRevLett.104.142502. PMID 20481935. https://www.researchgate.net/publication/44610795

  14. Zagrebaev, V. (2004). "Fusion-fission dynamics of super-heavy element formation and decay" (PDF). Nuclear Physics A. 734: 164–167. Bibcode:2004NuPhA.734..164Z. doi:10.1016/j.nuclphysa.2004.01.025. http://nrv.jinr.ru/pdf_file/npa_04.pdf

  15. Feng, Z; Jin, G; Li, J; Scheid, W (2009). "Production of heavy and superheavy nuclei in massive fusion reactions". Nuclear Physics A. 816 (1–4): 33–51. arXiv:0803.1117. Bibcode:2009NuPhA.816...33F. doi:10.1016/j.nuclphysa.2008.11.003. S2CID 18647291. /wiki/ArXiv_(identifier)

  16. "List of experiments 2000–2006". Univerzita Komenského v Bratislave. Archived from the original on July 23, 2007. https://web.archive.org/web/20070723094218/http://opal.dnp.fmph.uniba.sk/~beer/experiments.php

  17. "Both neutron properties and new results at SHE Factory". http://www.jinr.ru/posts/both-neutron-properties-and-new-results-at-she-factory/

  18. Ibadullayev, Dastan (2024). "Synthesis and study of the decay properties of isotopes of superheavy element Lv in Reactions 238U + 54Cr and 242Pu + 50Ti". jinr.ru. Joint Institute for Nuclear Research. Retrieved 2 November 2024. https://indico.jinr.ru/event/4343/contributions/28663/attachments/20748/36083/U%20+%20Cr%20AYSS%202024.pptx

  19. C. Samanta; P. Roy Chowdhury; D. N. Basu (2007). "Predictions of alpha decay half lives of heavy and superheavy elements". Nucl. Phys. A. 789 (1–4): 142–154. arXiv:nucl-th/0703086. Bibcode:2007NuPhA.789..142S. doi:10.1016/j.nuclphysa.2007.04.001. S2CID 7496348. /wiki/ArXiv_(identifier)

  20. Zagrebaev, V. (2004). "Fusion-fission dynamics of super-heavy element formation and decay" (PDF). Nuclear Physics A. 734: 164–167. Bibcode:2004NuPhA.734..164Z. doi:10.1016/j.nuclphysa.2004.01.025. http://nrv.jinr.ru/pdf_file/npa_04.pdf

  21. Zagrebaev, V. (2004). "Fusion-fission dynamics of super-heavy element formation and decay" (PDF). Nuclear Physics A. 734: 164–167. Bibcode:2004NuPhA.734..164Z. doi:10.1016/j.nuclphysa.2004.01.025. http://nrv.jinr.ru/pdf_file/npa_04.pdf

  22. Feng, Z; Jin, G; Li, J; Scheid, W (2009). "Production of heavy and superheavy nuclei in massive fusion reactions". Nuclear Physics A. 816 (1–4): 33–51. arXiv:0803.1117. Bibcode:2009NuPhA.816...33F. doi:10.1016/j.nuclphysa.2008.11.003. S2CID 18647291. /wiki/ArXiv_(identifier)

  23. Feng, Z; Jin, G; Li, J; Scheid, W (2009). "Production of heavy and superheavy nuclei in massive fusion reactions". Nuclear Physics A. 816 (1–4): 33–51. arXiv:0803.1117. Bibcode:2009NuPhA.816...33F. doi:10.1016/j.nuclphysa.2008.11.003. S2CID 18647291. /wiki/ArXiv_(identifier)

  24. Zhu, L.; Su, J.; Zhang, F. (2016). "Influence of the neutron numbers of projectile and target on the evaporation residue cross sections in hot fusion reactions". Physical Review C. 93 (6): 064610. Bibcode:2016PhRvC..93f4610Z. doi:10.1103/PhysRevC.93.064610. https://www.researchgate.net/publication/304366659