Reinecke's salt is an inorganic compound with the formula NH4[Cr(NCS)4(NH3)2]·H2O. The dark-red crystalline compound is soluble in boiling water, acetone, and ethanol. It can be classified as a metal isothiocyanate complex.
Structure, preparation, reactions
The chromium atom is surrounded by six nitrogen atoms in an octahedral geometry. The NH3 ligands are mutually trans and the Cr–NCS groups are linear. The salt crystallizes with one molecule of water.2
It was first reported in 1863.3 NH4[Cr(NCS)4(NH3)2] is prepared by treatment of molten NH4SCN (melting point around 145–150 °C) with (NH4)2Cr2O7.4
This salt was once widely used to precipitate primary and secondary amines as their ammonium salts. Included in the amines that effectively form crystalline precipitates are those derived from the amino acids, including proline and hydroxyproline. It also reacts with Hg2+ compounds, giving a red color or a red precipitate.
References
Peppel, T.; Schmidt, C.; Köckerling, M. (2011). "Synthesis, Properties, and Structures of Salts with the Reineckate Anion, [CrIII(NCS)4(NH3)2]−, and Large Organic Cations". Zeitschrift für Anorganische und Allgemeine Chemie. 637 (10): 1314–1321. doi:10.1002/zaac.201100091. /wiki/Doi_(identifier) ↩
Saito, Y.; Takeuchi, Y.; Pepinsky, R. (1955). "The Crystal Structure of Ammonium Reineckate". Zeitschrift für Kristallographie, Kristallgeometrie, Kristallphysik, Kristallchemie. 106 (1–6): 476–477. doi:10.1524/zkri.1954.106.16.476. S2CID 101134761. /wiki/Doi_(identifier) ↩
Reinecke, A. (1863). "Über Rhodanchromammonium-Verbindungen". Annalen der Chemie und Pharmacie. 126: 113–118. doi:10.1002/jlac.18631260116. https://zenodo.org/record/1427195 ↩
Dakin, H. D. (1935). "Reinecke Salt". Organic Syntheses. 15: 74. doi:10.15227/orgsyn.015.0074. /wiki/Organic_Syntheses ↩