Helium-4 (4He) is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consists of two protons and two neutrons.
Helium-4 makes up about one quarter of the ordinary matter in the universe by mass, with almost all of the rest being hydrogen. While nuclear fusion in stars also produces helium-4, most of the helium-4 in the Sun and in the universe is thought to have been produced during the Big Bang, known as "primordial helium". However, primordial helium-4 is largely absent from the Earth, having escaped during the high-temperature phase of Earth's formation. On Earth, most naturally occurring helium-4 is produced by the alpha decay of heavy elements in the Earth's crust, after the planet cooled and solidified.
When liquid helium-4 is cooled to below 2.17 K (−270.98 °C), it becomes a superfluid, with properties very different from those of an ordinary liquid. For example, if superfluid helium-4 is placed in an open vessel, a thin Rollin film will climb the sides of the vessel, causing the liquid to escape. The total spin of the helium-4 nucleus is an integer (zero), making it a boson. The superfluid behavior is a manifestation of Bose–Einstein condensation, which occurs only in collections of bosons.
It is theorized that at 0.2 K and 50 atm, solid helium-4 may be a superglass (an amorphous solid exhibiting superfluidity).