Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be synthesized and identified was 239Np in 1940, produced by bombarding 238U with neutrons to produce 239U, which then underwent beta decay to 239Np.
Trace quantities are found in nature from neutron capture reactions by uranium atoms, a fact not discovered until 1951.
Twenty-five neptunium radioisotopes have been characterized, with the most stable being 237Np with a half-life of 2.14 million years, 236Np with a half-life of 154,000 years, and 235Np with a half-life of 396.1 days. All of the remaining radioactive isotopes have half-lives that are less than 4.5 days, and the majority of these have half-lives that are less than 50 minutes. This element also has five meta states, with the most stable being 236mNp (t1/2 22.5 hours).
The isotopes of neptunium range from 219Np to 244Np, though the intermediate isotope 221Np has not yet been observed. The primary decay mode before the most stable isotope, 237Np, is electron capture (with a good deal of alpha emission), and the primary mode after is beta emission. The primary decay products before 237Np are isotopes of uranium and protactinium, and the primary products after are isotopes of plutonium. Neptunium is the heaviest element for which the location of the proton drip line is known; the lightest bound isotope is 220Np.