The Keggin structure is the best known structural form for heteropoly acids. It is the structural form of α-Keggin anions, having a general formula of [XM12O40]n−, where X is the heteroatom (most commonly are pentavalent phosphorus PV, tetravalent silicon SiIV, or trivalent boron BIII), M is the addendum atom (most common are molybdenum Mo and tungsten W), and O represents oxygen. The structure self-assembles in acidic aqueous solution and is a commonly used as a type of polyoxometalate catalysts.