High-temperature superconductivity (high-Tc or HTS) is superconductivity in materials with a critical temperature (the temperature below which the material behaves as a superconductor) above 77 K (−196.2 °C; −321.1 °F), the boiling point of liquid nitrogen. They are "high-temperature" only relative to previously known superconductors, which function only closer to absolute zero. The first high-temperature superconductor was discovered in 1986 by IBM researchers Georg Bednorz and K. Alex Müller. Although the critical temperature is around 35.1 K (−238.1 °C; −396.5 °F), this material was modified by Ching-Wu Chu to make the first high-temperature superconductor with critical temperature 93 K (−180.2 °C; −292.3 °F). Bednorz and Müller were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-Tc materials are type-II superconductors.
The major advantage of high-temperature superconductors is that they can be cooled using liquid nitrogen, in contrast to previously known superconductors, which require expensive and hard-to-handle coolants, primarily liquid helium. A second advantage of high-Tc materials is they retain their superconductivity in higher magnetic fields than previous materials. This is important when constructing superconducting magnets, a primary application of high-Tc materials.
The majority of high-temperature superconductors are ceramics, rather than the previously known metallic materials. Ceramic superconductors are suitable for some practical uses but encounter manufacturing issues. For example, most ceramics are brittle, which complicates wire fabrication.
The main class of high-temperature superconductors is copper oxides combined with other metals, especially the rare-earth barium copper oxides (REBCOs) such as yttrium barium copper oxide (YBCO). The second class of high-temperature superconductors in the practical classification is the iron-based compounds. Magnesium diboride is sometimes included in high-temperature superconductors: It is relatively simple to manufacture, but it superconducts only below 39 K (−234.2 °C), which makes it unsuitable for liquid nitrogen cooling.