The atmosphere contains a range of compounds in small quantities, including some based on hydrogen, such as hydrogen chloride (HCl) and hydrogen fluoride (HF). There is carbon monoxide, water vapour and atomic oxygen as well. Hydrogen is in relatively short supply in the Venusian atmosphere. A large amount of the planet's hydrogen is theorised to have been lost to space, with the remainder being mostly bound up in water vapour and sulfuric acid (H2SO4). Strong evidence of significant hydrogen loss over the historical evolution of the planet is the very high D–H ratio measured in the Venusian atmosphere. The ratio is about 0.015–0.025, which is 100–150 times higher than the terrestrial value of 1.6×10−4. According to some measurements, in the upper atmosphere of Venus D/H ratio is 1.5 higher than in the bulk atmosphere.
Atmospheric compositionAbsorption spectrum of a simple gas mixture corresponding to In 2022, no phosphine detection with an upper limit concentration of 0.8 ppb was announced for Venusian altitudes of 75–110 km.
The ammonia in the atmosphere of Venus was tentatively detected by two atmospheric probes - Venera 8 and Pioneer Venus Multiprobe, although the detection was rejected that time due to poorly characterized sensors behavior in Venusian environment and ammonia believed to be chemically unstable in the strongly oxidizing atmosphere of Venus.
The atmosphere is divided into a number of sections depending on altitude. The densest part of the atmosphere, the troposphere, begins at the surface and extends upwards to 65 km. The winds are slow near the surface, but at the top of the troposphere the temperature and pressure reaches Earth-like levels and clouds pick up speed to 100 m/s (360 km/h).
The atmospheric pressure at the surface of Venus is about 92 times that of the Earth, similar to the pressure found 900 m (3,000 ft) below the surface of the ocean. The atmosphere has a mass of 4.8×1020 kg, about 93 times the mass of the Earth's total atmosphere. The density of the air at the surface is 65 kg/m3, which is 6.5% that of liquid water on Earth. The pressure found on Venus's surface is high enough that the carbon dioxide is technically no longer a gas, but a supercritical fluid. This supercritical carbon dioxide forms a kind of sea, with 6.5% the density of water, that covers the entire surface of Venus. This sea of supercritical carbon dioxide transfers heat very efficiently, buffering the temperature changes between night and day (which last 56 terrestrial days). Particularly at possible higher atmospheric pressures in Venus's past might have created an even more fluid-like layer of supercritical carbon dioxide shaping Venus's landscape; altogether, it is unclear how the supercritical environment behaves and is shaped.
The troposphere on Venus contains 99% of the atmosphere by mass. 90% of the atmosphere of Venus is within 28 km (17.5 mi) of the surface; by comparison, 90% of the atmosphere of Earth is within 16 km (10 mi) of the surface. At a height of 50 km (31 mi) the atmospheric pressure is approximately equal to that at the surface of Earth. On the night side of Venus clouds can still be found at 80 km (50 mi) above the surface.
The altitude of the troposphere most similar to Earth is near the tropopause—the boundary between troposphere and mesosphere. It is located slightly above 50 km. According to measurements by the Magellan and Venus Express probes, the altitude from 52.5 to 54 km has a temperature between 293 K (20 °C) and 310 K (37 °C), and the altitude at 49.5 km above the surface is where the pressure becomes the same as Earth at sea level. As crewed ships sent to Venus would be able to compensate for differences in temperature to a certain extent, anywhere from about 50 to 54 km or so above the surface would be the easiest altitude in which to base an exploration or colony, where the temperature would be in the crucial "liquid water" range of 273 K (0 °C) to 323 K (50 °C) and the air pressure the same as habitable regions of Earth. As CO2 is heavier than air, the colony's air (nitrogen and oxygen) could keep the structure floating at that altitude like a dirigible.
The mesosphere of Venus can be divided into two layers: the lower one between 62 and 73 km and the upper one between 73 and 95 km. In the first layer the temperature is nearly constant at 230 K (−43 °C). This layer coincides with the upper cloud deck. In the second layer, the temperature starts to decrease again, reaching about 165 K (−108 °C) at the altitude of 95 km, where mesopause begins. It is the coldest part of the Venusian dayside atmosphere. In the dayside mesopause, which serves as a boundary between the mesosphere and thermosphere and is located between 95 and 120 km, temperature increases to a constant—about 300–400 K (27–127 °C)—value prevalent in the thermosphere. In contrast, the nightside Venusian thermosphere is the coldest place on Venus with temperature as low as 100 K (−173 °C). It is even called a cryosphere.
The circulation patterns in the upper mesosphere and thermosphere of Venus are completely different from those in the lower atmosphere. At altitudes 90–150 km the Venusian air moves from the dayside to nightside of the planet, with upwelling over sunlit hemisphere and downwelling over dark hemisphere. The downwelling over the nightside causes adiabatic heating of the air, which forms a warm layer in the nightside mesosphere at the altitudes 90–120 km. The temperature of this layer—230 K (−43 °C)—is far higher than the typical temperature found in the nightside thermosphere—100 K (−173 °C). The air circulated from the dayside also carries oxygen atoms, which after recombination form excited molecules of oxygen in the long-lived singlet state (1Δg), which then relax and emit infrared radiation at the wavelength 1.27 μm. This radiation from the altitude range 90–100 km is often observed from the ground and spacecraft. The nightside upper mesosphere and thermosphere of Venus is also the source of non-local thermodynamic equilibrium emissions of CO2 and nitric oxide molecules, which are responsible for the low temperature of the nightside thermosphere.
At the subsolar point the bow shock stands 1900 km (0.3 Rv, where Rv is the radius of Venus) above the surface of Venus. This distance was measured in 2007 near the solar activity minimum. Near the solar activity maximum it can be several times further from the planet. The magnetopause is located at the altitude of 300 km. The upper boundary of the ionosphere (ionopause) is near 250 km. Between the magnetopause and ionopause there exists a magnetic barrier—a local enhancement of the magnetic field, which prevents the solar plasma from penetrating deeper into the Venusian atmosphere, at least near solar activity minimum. The magnetic field in the barrier reaches up to 40 nT. The magnetotail continues up to ten radii from the planet. It is the most active part of the Venusian magnetosphere. There are reconnection events and particle acceleration in the tail. The energies of electrons and ions in the magnetotail are around 100 and 1000 eV respectively.
Venusian clouds are thick and are composed mainly (75–96%) of sulfuric acid droplets. These clouds obscure the surface of Venus from optical imaging, and reflect about 75% of the sunlight that falls on them. The geometric albedo, a common measure of reflectivity, is the highest of any planet in the Solar System. This high reflectivity potentially enables any probe exploring the cloud tops sufficient solar energy such that solar cells can be fitted anywhere on the craft. The density of the clouds is highly variable with the densest layer at about 48.5 km, reaching 0.1 g/m3 similar to the lower range of cumulonimbus storm clouds on Earth.
The cloud cover is such that it reflects more than 60% of the solar light Venus receives, leaving the surface with typical light levels of 14,000 lux, comparable to that on Earth "in the daytime with overcast clouds". The equivalent visibility is about three kilometers, but this will likely vary with the wind conditions. Little to no solar energy could conceivably be collected by solar panels on a surface probe. In fact, due to the thick, highly reflective cloud cover, the total solar energy received by the surface of the planet is less than that of the Earth, despite its proximity to the Sun.
In 2009, a prominent bright spot in the atmosphere was noted by an amateur astronomer and photographed by Venus Express. Its cause is currently unknown, with surface volcanism advanced as a possible explanation.
The Pioneer Venus Orbiter (PVO) was equipped with an electric field detector specifically to detect lightning and the Venera 13 and 14 missions included a radio receiver and point discharge sensor to search for thunderstorms. Other missions equipped with instruments that could search for lightning included Venera 9 which had a visible spectrometer; Pioneer which had a star sensor; and VEGA which had a photometer.
The mechanism generating lightning on Venus, if present, remains unknown. Whilst the sulfuric acid cloud droplets can become charged, the atmosphere may be too electrically conductive for the charge to be sustained, preventing lightning.
Lightning could potentially contribute to atmospheric chemistry, through heating which could break apart molecules that contain carbon, oxygen, sulfur, nitrogen, and hydrogen molecules (carbon dioxide, nitrogen gas, sulfuric acid, and water), that will recombine to form new molecules ("carbon oxides", "suboxides", "sulfur oxides", "oxygen", "elemental sulfur", "nitrogen oxides", "sulfuric acid clusters", "polysulfur oxides", "carbon soot", etc.). Lightning could contribute to the production of carbon monoxide and oxygen gas by converting sulfur and sulfur dioxide into sulfuric acid, and water and sulfuric dioxide to sulfur to sustain clouds. Regardless of how frequent lightning on Venus is, it is important to study as it can be a potential hazard for spacecraft.
Due to the harsh conditions on the surface, little of the planet has been explored; in addition to the fact that life as currently understood may not necessarily be the same in other parts of the universe, the extent of the tenacity of life on Earth itself has not yet been shown. Creatures known as extremophiles exist on Earth, preferring extreme habitats. Thermophiles and hyperthermophiles thrive at temperatures reaching above the boiling point of water, acidophiles thrive at a pH level of 3 or below, polyextremophiles can survive a varied number of extreme conditions, and many other types of extremophiles exist on Earth.
The surface temperature of Venus (over 450 °C) is far beyond the extremophile range, which extends only tens of degrees beyond 100 °C. However, the lower temperature of the cloud tops means that life could plausibly exist there, the same way that bacteria have been found living and reproducing in clouds on Earth. Any such bacteria living in the cloud tops, however, would have to be hyper-acidophilic, due to the concentrated sulfuric acid environment. Microbes in the thick, cloudy atmosphere could be protected from solar radiation by the sulfur compounds in the air.
The Venusian atmosphere has been found to be sufficiently out of equilibrium as to require further investigation. Analysis of data from the Venera, Pioneer, and Magellan missions has found hydrogen sulfide (later disputed) and sulfur dioxide (SO2) together in the upper atmosphere, as well as carbonyl sulfide (OCS). The first two gases react with each other, implying that something must produce them. Carbonyl sulfide is difficult to produce inorganically, but it is present in the Venusian atmosphere. However, the planet's volcanism could explain the presence of carbonyl sulfide. In addition, one of the early Venera probes detected large amounts of toxic chlorine just below the Venusian cloud deck.
Through studies of the present cloud structure and geology of the surface, combined with the fact that the luminosity of the Sun has increased by 25% since around 3.8 billion years ago, it is thought that the early environment of Venus was more like that of Earth with liquid water on the surface. At some point in the evolution of Venus, a runaway greenhouse effect occurred, leading to the current greenhouse-dominated atmosphere. The timing of this transition away from Earthlike is not known, but is estimated to have occurred around 4 billion years ago. The runaway greenhouse effect may have been caused by the evaporation of the surface water and the rise of the levels of greenhouse gases that followed. Venus's atmosphere has therefore received a great deal of attention from those studying climate change on Earth.
There are no geologic forms on the planet to suggest the presence of water over the past billion years. However, there is no reason to suppose that Venus was an exception to the processes that formed Earth and gave it its water during its early history, possibly from the original rocks that formed the planet or later on from comets. The common view among research scientists is that water would have existed for about 600 million years on the surface before evaporating, though some such as David Grinspoon believe that up to 2 billion years could also be plausible. This longer timescale for the persistence of oceans is also supported by General Circulation Model simulations incorporating the thermal effects of clouds on an evolving Venusian hydrosphere.
The upper atmosphere of Venus can be measured from Earth when the planet crosses the sun in a rare event known as a solar transit. The last solar transit of Venus occurred in 2012. Using quantitative astronomical spectroscopy, scientists were able to analyze sunlight that passed through the planet's atmosphere to reveal chemicals within it. As the technique to analyse light to discover information about a planet's atmosphere only first showed results in 2001, this was the first opportunity to gain conclusive results in this way on the atmosphere of Venus since observation of solar transits began. This solar transit was a rare opportunity considering the lack of information on the atmosphere between 65 and 85 km. The solar transit in 2004 enabled astronomers to gather a large amount of data useful not only in determining the composition of the upper atmosphere of Venus, but also in refining techniques used in searching for extrasolar planets. The atmosphere of mostly CO2, absorbs near-infrared radiation, making it easy to observe. During the 2004 transit, the absorption in the atmosphere as a function of wavelength revealed the properties of the gases at that altitude. The Doppler shift of the gases also enabled wind patterns to be measured.
A solar transit of Venus is an extremely rare event, and the last solar transit of the planet before 2004 was in 1882. The most recent solar transit was in 2012; the next one will not occur until 2117.
A craft called the Venus Mobile Explorer has been proposed by the Venus Exploration Analysis Group (VEXAG) to study the composition and isotopic measurements of the surface and the atmosphere, for about 90 days. The mission has not been selected for launch.
After missions discovered the reality of the harsh nature of the planet's surface, attention shifted towards other targets such as Mars. There have been a number of proposed missions afterward, however, and many of these involve the little-known upper atmosphere. The Soviet Vega program in 1985 dropped two balloons into the atmosphere, but these were battery-powered and lasted for only about two Earth days each before running out of power. Since then, there has been no exploration of the upper atmosphere. In 2002, the NASA contractor Global Aerospace proposed a balloon that would be capable of staying in the upper atmosphere for hundreds of Earth days as opposed to two.
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This thickness corresponds to the polar latitudes. It is narrower near the equator—65–67 km.
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